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Dithallous hydrogen phosphate, Tl2HPO4

Dithallous hydrogen phosphate, Tl2HPO4.H2O, may be prepared by neutralising a boiling solution of phosphoric acid with thallous carbonate, evaporating the liquid to a syrup, and allowing it to crystallise. The crystals are orthorhombic (a:b:c = 0.934:1:0.657) and isomorphous with sodium dihydrogen phosphate, NaH2PO4.H2O. The anhydrous salt has a density of 1.779.

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