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Thallous hypophosphite, TlH2PO2

Thallous hypophosphite, TlH2PO2, is a sparingly soluble salt which crystallises in rhombic bipyramids (a:b:c = 0.786:1:0.806). It melts at 150°, and at higher temperatures decomposes, evolving phosphine and leaving a residue of thallous meta- and pyro-phosphates.

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